Title of article
Synthesis and characterization of a rare hemiacetalate bridged incomplete image dicubane cluster
Author/Authors
Kartik Chandra Mondal، نويسنده , , Oindrila Sengupta، نويسنده , , Partha Sarathi Mukherjee، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
4
From page
682
To page
685
Abstract
Reaction of 2-pyridinecarboxaldehyde [(Py)CHO] with Cu(NO3)2·2.5H2O in the presence of 4-aminopyridine and NaN3 in MeOH lead to an incomplete double-cubane [Cu4{PyCH(O)(OMe)}4(N3)4] (1) in 87% isolated yield, representing a rare type of metal cluster containing bridging hemiacetalate ligand [pyCH(O)(OMe)]−1 which was characterized by single crystal structure analysis and variable temperature magnetic behavior.
Keywords
Antiferromagnetic , Azide , crystal structure , Copper(II)
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318173
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