Title of article
An intertwined double chain constructed by [SiMo12O40]4− clusters and unusual [Cu2(DF)2H2O] dimers
Author/Authors
Haijun Pang، نويسنده , , Jingquan Sha، نويسنده , , Jun Peng، نويسنده , , Aixiang Tian، نويسنده , , Chunjing Zhang، نويسنده , , Pengpeng Zhang، نويسنده , , Yuan Chen، نويسنده , , Min Zhu، نويسنده , , Yonghui Wang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
4
From page
735
To page
738
Abstract
A new compound, {[Cu2(DF)2H2O]2SiMo12O40} (1) (DF = 4,5-diazafluoren-9-one), has been hydrothermally synthesized and characterized by routine methods and single crystal X-ray diffraction. In 1, all the DF only adopt the unusual bidentate coordination mode for the first time coordinating to Cu atoms to form copper-dimers which link [SiMo12O40]4− clusters obtaining an intertwined double chain. Furthermore, the luminescent and electrochemical properties of the title compound have been studied.
Keywords
5-diazafluoren-9-one , 4 , Bidentate coordination mode , Luminescent and electrochemical properties , Polyoxometalates
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318187
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