Title of article
New (κ2-C,N)-palladacyclic complexes with benzimidazol-2-ylidene ligand: Synthesis, crystal structures and characterization
Author/Authors
M. Emin Günay، نويسنده , , Rukiye Gümü?ada، نويسنده , , Nam?k ?zdemir، نويسنده , , Muharrem Dinçer، نويسنده , , Bekir Cetinkaya، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
4
From page
990
To page
993
Abstract
Reaction of unsymmetrical benzimidazolium bromides (1) with Ag2O and subsequent transmetallation with chloro-bridged dinuclear palladacycle, [Pd(dmba)(μ-Cl)]2 (dmba: N,N-dimethylbenzylamine) afforded benzannulated monocarbene complexes [Pd(dmba)(NHC)Cl], 2. The palladacycles (2a–c) were characterized by elemental analysis; NMR spectroscopy and the molecular structure of 2a and 2c were determined by X-ray crystallography.
Keywords
N-heterocyclic carbene , crystal structure , Palladacycles , Unsymmetrical benzimidazolium salt
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318255
Link To Document