Title of article :
A new synthetic route towards a Ru(III) substituted heteropolytungstate anion
Author/Authors :
Claire Besson، نويسنده , , Su Wen Chen، نويسنده , , Richard Villanneau، نويسنده , , Guillaume Izzet، نويسنده , , Anna Proust، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Abstract :
Microwave irradiation of a mixture of K7[PW11O39]·14H2O and [Ru(dmf)6](CF3SO3)3 allowed the straightforward hydrothermal synthesis of the Keggin-type [PW11O39RuIII(OH2)]4− anion. Physical characterizations of the corresponding tetrabutylammonium (TBA) salt are herein described. This study provides a complete set of spectroscopic and electrochemical references for RuIII-incorporating heteropolytungstates.
Keywords :
XANES , Microwave activation , Ruthenium , Polyoxometalates , EPR spectroscopy
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
