Title of article
The structural characterization and hydroformylation activity of the tri-rhodium complex [Rh3(μ2-dppm)2(μ2-CO)3(K1-CO)3]BF4
Author/Authors
Fabio Lorenzini، نويسنده , , Eoghain O’Hara، نويسنده , , Shimeng Qian، نويسنده , , Fabio Marchetti، نويسنده , , James M. Birbeck، نويسنده , , Anthony Haynes، نويسنده , , Alexander J. Blake، نويسنده , , Graham C. Saunders، نويسنده , , Andrew C. Marr، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
3
From page
1071
To page
1073
Abstract
Rh2(cod)2(μ2-dppm)(μ2-Cl)]BF4 (1) rearranges under carbon monoxide to give [Rh3(μ2-dppm)2(μ2-CO)3(K1-CO)3]BF4 (2). Complex 2 has been structurally characterized by single crystal X-ray crystallography. The hydroformylation activities of 1 and 2 were compared for substrates styrene and 1-hexene and the activity of 2 found to be unexpectedly high.
Keywords
Binuclear , Trinuclear , Rhodium , hydroformylation
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318277
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