Title of article :
A new multi-cobalt-substituted C-shaped polyoxotungstogermanate, [((CoOH2)Co2GeW9O34)2(GeW6O26)]20−
Author/Authors :
Tong Ruizhan، نويسنده , , Lili Chen، نويسنده , , Ying Liu، نويسنده , , Bin Liu، نويسنده , , Ganglin Xue، نويسنده , , Huaiming Hu، نويسنده , , Feng Fu، نويسنده , , Jiwu Wang، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
A new multi-cobalt-substituted polyoxogermanotungstate Na20[((CoOH2)Co2GeW9O34)2(GeW6O26)]·47H2O has been synthesized and characterized by IR spectroscopy, UV electronic and luminescent spectroscopy, elemental analysis and single-crystal X-ray diffraction. Polyanion [((CoOH2)Co2GeW9O34)2(GeW6O26)]20− consists of two [B-α-(CoOH2)Co2GeW9O34]4− units linked via a unique B-type hexavacant GeW6O2612− fragment, leading to a C-shaped structure with C2v symmetry. This is the first report of the C-shaped multi-cobalt-substituted polyoxotungstogermanate.
Keywords :
Polyoxometalates , Cobalt , Structure elucidation , Germanium , Sandwich-type
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
