Title of article
Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases
Author/Authors
Martin Jarenmark، نويسنده , , H?kan Carlsson، نويسنده , , Vladimir M. Trukhan، نويسنده , , Matti Haukka، نويسنده , , Sophie E. Canton، نويسنده , , Monica Walczak، نويسنده , , Wilfred Fullagar، نويسنده , , Villy Sundstr?m، نويسنده , , Ebbe Nordlander، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
4
From page
334
To page
337
Abstract
The heterodinuclear complexes [FeZn(L)(CH3CO2)2]+ (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases. They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases.
Keywords
Dinuclear , Transesterification , Model complexes , HPNP , Iron , zinc , Bioinorganic chemistry , Heterodinuclear , Purple acid phosphatase
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318410
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