Title of article
A chiral helical Mn(II) MOF showing unusual utg topology based on d-saccharic acid
Author/Authors
Yao-Kang Lv، نويسنده , , Cai-Hong Zhan، نويسنده , , Zhan-Guo Jiang، نويسنده , , Yunlong Feng، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
5
From page
440
To page
444
Abstract
A chiral helical MOF [Mn2(sac)2(H2O)2]·3.3H2O (H2sac = d-saccharic acid) (1) has been synthesized and characterized. MOF 1 crystallizes in orthorhombic system with space group P212121, and the structure contains right-handed 21 helical chains in three directions with hydrophilic channels. From the topological point of view, the framework of MOF 1 can be abstracted as an unusual binodal 3-connected network with utg topology. The electrochemical property has been studied, undergoing two one-electron redox processes.
Keywords
d-saccharic acid , Metal-organic framework , topology , Chiral net , Cyclic voltammetry
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318437
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