Title of article
Synthesis and structural characterization of the novel unusual oxido-bridged rhenium complex with Re atoms in two different coordination environments
Author/Authors
Andrzej Kochel، نويسنده , , Ma?gorzata Ho?y?ska، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
4
From page
782
To page
785
Abstract
A new binuclear mixed-valence complex [ReCl4(py)(μ-O)Re(py)4Cl]·2py was obtained by solvothermal synthesis in a Berghoff autoclave. It has been studied by IR, reflectance spectra, TGA and X-ray measurements, which support the assumption, that two Re centres with different coordination environments are present. Most plausible, yet not unambiguous oxidation state assignment is ReIII/IV.
Keywords
Rhenium mixed-valence complex , crystal structure , Solvothermal synthesis
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318524
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