Title of article
A hexanuclear cerium(IV) cluster with mixed coordination environment
Author/Authors
Rajorshi Das، نويسنده , , Rupam Sarma، نويسنده , , Jubaraj B. Baruah، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
3
From page
793
To page
795
Abstract
Synthesis and structure of a modified intermediate derived from ammonium cerium(IV) nitrate for oxidative reactions as a hexanuclear cerium(IV) complex that has cerium ions in two different coordination environment is reported. The complex having ability to oxidise three moles of catechol to corresponding quinone has a composition NH4[Ce6(µ3-O)5(µ3-OH)3(µ2-C6H5COO)9(NO3)3(DMF)3].DMF.H2O is prepared under room temperature and is characterised by X-ray crystallography.
Keywords
Hexanuclear cluster , Benzoate complex , Mixed coordination environment , oxidant , Ammonium cerium(IV) nitrate
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318527
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