Title of article :
The first (tricarbollide)rhodium halide complexes
Author/Authors :
Dmitry A. Loginov، نويسنده , , Zoya A. Starikova، نويسنده , , Pavel V. Petrovskii، نويسنده , , Josef Holub، نويسنده , , Alexander R. Kudinov، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Abstract :
Reactions of (η-1-tBuNH-1,7,9-C3B8H10)Rh(cod) with Br2 or I2 give complexes [(η-1-tBuNH-1,7,9-C3B8H10)RhX2]2 (X = Br (2a), I (2b)). Reaction of 2b with TlBF4 affords cation [(η-1-tBuNH-1,7,9-C3B8H10)2Rh2(μ-I)3]+ (3). Complex 2a reacts with Tl[Tl(η-7,8-C2B9H11)] giving the bis(carborane) complex (η-1-tBuNH-1,7,9-C3B8H10)Rh(η-7,8-C2B9H11) (4). Structures of 2a,b were determined by X-ray diffraction.]
Keywords :
Boranes , Metallacarboranes , Tricarbollide , Rhodium
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
