Title of article :
A Fe17 cluster with S = 35/2 ground state: Synthesis, structure, and magnetic properties
Author/Authors :
Zhi-Guo Gu، نويسنده , , Baoxiang Wang، نويسنده , , Jing-Jing Na، نويسنده , , Xin-Hui Zhou، نويسنده , , Zaijun Li، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Abstract :
A new polyiron complex [Fe17(OH)7O11(O2CPh)20(N3)2]·4H2O·10MeCN (1), with compact [Fe17(OH)7O11] core encapsulated by twenty benzoate anions and two end-on (EO) azido ligands has been synthesized and structurally characterized. Intramolecular antiferromagnetic couplings are observed for 1 and it has S = 35/2 ground state which was confirmed by magnetic measurements and Mössbauer spectra.
Keywords :
Oxo/azido-bridged cluster , Self-assembly , Benzoate ligand , Iron(III)
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
