Author/Authors :
Gao-Wen Yang، نويسنده , , Dianyu Chen، نويسنده , , Chun Zhai، نويسنده , , Xiao-Yan Tang، نويسنده , , Qiao-Yun Li، نويسنده , , Feng Zhou، نويسنده , , Zhu-Feng Miao، نويسنده , , Jian-Ning Jin، نويسنده , , Hong-Dan Ding، نويسنده ,
Abstract :
A novel 1D coordination compound [Pr2(tza)3(H2O)6]n·4nH2O (1) (tza = tetrazole-5-acetato) was synthesized by the reaction of tetrazole-5-acetic acid with Pr(NO3)3·6H2O in the presence of KOH. This complex showed a specific and good catalytic behavior in the polymerization of styrene. The high molecular weight polymers with narrow molecular weight distributions in good yields were obtained within a few minutes.
Keywords :
Praseodymium(III) , Tetrazole-5-acetato , crystal structure , Catalytic property , Coordination polymer
