Title of article :
Synthesis and crystal structure of the first five-membered ansa-metallacyclocumulene rac-(ebthi)Zr(η4-t-Bu-C4-t-Bu)
Author/Authors :
Vladimir V. Burlakov، نويسنده , , Yulia V. Nelyubina، نويسنده , , Konstantin A. Lyssenko، نويسنده , , Vladimir B. Shur، نويسنده , , Perdita Arndt، نويسنده , , Katharina Kaleta، نويسنده , , Wolfgang Baumann، نويسنده , , Uwe Rosenthal، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Pages :
3
From page :
975
To page :
977
Abstract :
The zirconocene alkyne complex rac-(ebthi)Zr(η2-Me3SiC2SiMe3) (1) reacts with 1,4-bis-tert-butyl-buta-1,3-diyne to yield the novel five-membered metallacyclocumulene rac-(ebthi)Zr(η4-t-Bu-C4-t-Bu) (2) (ebthi = 1,2-ethylene-1,1′-bis(η5-tetrahydroindenyl)), t-Bu = tert-butyl). The structure of 2 was confirmed by X-ray studies.
Keywords :
zirconocene , rac-(ebthi) , Metallacyclocumulene , ansa-metallocene , crystal structure
Journal title :
Inorganic Chemistry Communications
Serial Year :
2011
Journal title :
Inorganic Chemistry Communications
Record number :
1318970
Link To Document :
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