Title of article
The one-electron reduction of a multi-centred iron(III) polyoxometallate. A pulse radiolysis study
Author/Authors
Inna Popivker، نويسنده , , Israel Zilbermann، نويسنده , , Eric Maimon، نويسنده , , Haim Cohen، نويسنده , , Dan Meyerstein، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
3
From page
1390
To page
1392
Abstract
The single electron reduction of the complex [P8W48O184Fe16(OH)28(H2O)4]20− by the hydrated electron yields the mixed-valence complex [P8W48O184FeIIFeIII15(OH)28–(H2O)4]21− which has an intervalence charge transfer band in the near I.R. This result points out that there is a strong interaction between the iron centres. The formation of [P8W48O184FeIIFeIII15–(OH)28(H2O)4]21− is followed by the loss of the FeII centre and the rearrangement of the remaining Fe15III cluster.
Keywords
Mixed-valence , Pulse-radiolysis , Polyoxometallates , Inter-valence charge transfer , Iron oxide nanocluster , Single electron reduction
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1319070
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