Author/Authors :
Young Hoon Lee، نويسنده , , Yasuka Komatsu، نويسنده , , Yuuki Yamamoto، نويسنده , , Kazuya Kato، نويسنده , , Tetsuya Shimizu، نويسنده , , Asuka Ohta، نويسنده , , Takeshi Matsui، نويسنده , , Shinya Hayami، نويسنده ,
Abstract :
Novel 1-D polymeric metallo-organic triazole iron(II) complex {[Fe(C5C12C10-trz)3](ClO4)2}n (1) with branched long alkyl chain was synthesized and characterized in detail. The compound exhibited liquid crystal transition and spin crossover behavior. The liquid crystal transition occurred at 233 K, and the spin crossover was observed at T1/2↑ = 250 K and T1/2↓ = 248 K.
Keywords :
Spin crossover , Branched long alkyl chain , Polymeric iron(II) complex , Phase transition
