Title of article :
Specific molecular container for dioxane: Ionic metallacyclodimeric palladium(II) complex
Author/Authors :
Jungmin Ahn، نويسنده , , Kyung Hwan Park، نويسنده , , Tae Hwan Noh، نويسنده , , Ok-Sang Jung*، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Abstract :
Metallacyclodimeric complex of [(Me4en)Pd(L)]2(PF6)4 (Me4en = N,N,N′,N′-tetramethylethylenediamine; L = 1,3-bis(4-pyridyl)tetramethyldisiloxane) is a sensitive container for dioxane via appropriate size effect. The equilibrium between the “included” and “free” dioxane species has been monitored by temperature-dependent 1H NMR spectra.
Keywords :
Palladium(II) complex , Metallacyclodimer , 1 , 3-Bis(4-pyridyl)tetramethyldisiloxane , 1 , 4-Dioxane recognition , host–guest chemistry
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
