Title of article
A new eight-connected CsCl-type topological net based on trinuclear Co(II) clusters as nodes
Author/Authors
Yien Du، نويسنده , , Xiaofang Wang ، نويسنده , , Yanfang Liang، نويسنده , , Jian-Wei Ji، نويسنده , , Zhengbo Han، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
1940
To page
1943
Abstract
Ionothermal reaction of isophthalate (H2ip), and colbolt(II) nitrate under 1-ethly-3-methylimidazolium bromide (EMimBr) as solvent leads to a novel three dimensional metal–organic framework (EMim)2[Co3(ip)4] (1). It can be described as an eight-connected CsCl-type net (42464) utilizing trinuclear Co(II) clusters as eight-connected nodes and ip ligands as linkers. The imidazolium cation [EMim]+ of the ionic liquid acting as charge-compensating agents has interactions with the framework. The magnetic properties studies show ferrimagnetic behavior for 1.
Keywords
Ionothermal synthesis , Ionic liquid , Metal–organic framework , Trinuclear building unit
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1319197
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