Title of article
A novel 3D polyoxometalate-linked polypseudo-rotaxane framework by using semi-rigid bis(triazole) ligand
Author/Authors
Xiuli Wang، نويسنده , , Xiaojing Liu، نويسنده , , Aixiang Tian، نويسنده , , Jun Ying، نويسنده , , Hongyan Lin، نويسنده , , Guocheng Liu، نويسنده , , Juwen Zhang، نويسنده , , Dan Zhao، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
4
From page
71
To page
74
Abstract
A novel 3D polyoxometalate-linked polypseudo-rotaxane framework, [Cu(L)2(HPWVI10WV2O40)][Cu(L)(H2O)4]⋅4H2O (1) (L = 4,4′-bis(1,2,4-triazol-1-ylmethyl)biphenyl), was synthesized under hydrothermal conditions. Compound 1 contains a 2D grid-like sheet, which is constructed from bi-nuclear [Cu2L2]4 + cycles and Keggin anion linkages. The 1D polymeric [CuL(H2O)4]2 + chains penetrate the 2D sheets at an inclined angle to generate an interesting 3D polypseudo-rotaxane architecture.
Keywords
Hydrothermal synthesis , Semi-rigid bis(triazole) ligand , Polypseudo-rotaxane , Keggin polyoxometalate
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319331
Link To Document