Title of article :
Diastereomerism in tetranuclear copper(II) complexes of a phenol based “end-off” compartmental ligand
Author/Authors :
Debasis Das، نويسنده , , Averi Guha، نويسنده , , Sudhanshu Das، نويسنده , , Prateeti Chakraborty، نويسنده , , ANIMESH KUMAR CHAKRABORTY and TAPAN KUMAR MONDAL، نويسنده , , Somen Goswami، نويسنده , , Ennio Zangrando، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
Two diastereomeric forms of the μ4-oxo-bridged tetranuclear copper(II) complex [Cu4(O)(L)2(Ac)4] (where L = N2,O-donor Schiff-base ligand and Ac = acetate anion), differing for the bridging arrangement of the carboxylate groups, were individually synthesized and structurally characterized. Their formation was rationalized by DFT calculation and their catecholase-like activity was studied.
Keywords :
Tetranuclear Cu(II) , Diastereomeric Cu(II) complex , crystal structure , DFT study , Catecholase activity , ESI-MS study
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
