Title of article :
Photolysis of Zeise salt in aqueous solution: Photocatalysis of the hydration of olefins to alcohols
Author/Authors :
Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
PtIICl3(C2H4)]− + 2 H2O ―hν→ [PtII(H2O)Cl3] − + CH3CH2OH
Since [Pt(H2O)Cl3]− adds again ethylene to regenerate [Pt(C2H4)Cl3]− the overall reaction proceeds as a photocatalysis converting C2H4 to C2H5OH. When ethylene was replaced by 1‐hexene the photoaquation to 1‐hexanol takes place with TON > 2.30.
Keywords :
Coordination chemistry , Photocatalysis , Zeise salt , Platinum complexes , Olefin complexes , Photochemistry
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
