Title of article
Electrochemical synthesis of a tetrahedral trinuclear nickel(II) complex with a tridentated arenephosphinothiol ligand
Author/Authors
Patricia Fern?ndez-Souto، نويسنده , , Jaime Romero، نويسنده , , J. Arturo Garc?a-V?zquez، نويسنده , , Antonio Sousa، نويسنده , , Paulo Pérez-Lourido، نويسنده , , Laura Valencia، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
3
From page
28
To page
30
Abstract
A trinuclear Ni(II) complex with the tridentated aromatic phosphinothiol ligand PhP(C6H4SH-2)2 has been obtained by an electrochemical procedure. The crystal structure shows that the three Ni(II) ions are in a different distorted tetrahedral environment. The denticity and flexibility of the ligand permit the tetrahedral geometry instead of the square planar geometry, the most stable geometrical state for Ni(II) d8 systems.
Keywords
Nickel(II) , Phosphinothiol ligand , Electrochemical synthesis , Trinuclear complex , X-ray crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319696
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