Title of article :
[Ni(dien)2]3[Ge3Sb8S21]·0.5H2O: A new 2-D layered thiogermanate–thioantimonate with metal complexes as template ions
Author/Authors :
Jian Zhou، نويسنده , , Xing Liu، نويسنده , , Guoming Liang، نويسنده , , Weijiang Liang، نويسنده , , Feilong Hu، نويسنده , , Ligang Zhu، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
A new 2-D layered thiogermanate–thioantimonate [Ni(dien)2]3[Ge3Sb8S21]·0.5H2O (1, dien = diethylenetriamine) was synthesized under solvothermal conditions and structurally characterized. The polymeric [Ge3Sb8S21]6n−n anion in 1 is composed of heterometallic semicube [GeSb2S7] clusters and trigonal-pyramidal [SbS3] units, which are interconnected to build a 2-D layer with the large Sb18S18 heterorings. The apertures of the Sb18S18 heterorings are filled by three [Ni(dien)2]2+ complex cations as template ions. The absorption band edge of 1 is 2.29 eV, exhibiting properties of the semiconductor.
Keywords :
Thioantimonate , Solvothermal synthesis , Transition metal complex , crystal structure , Thiogermanate
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
