Title of article
Oxygenation of organic sulfides catalyzed by simple Fe(III) salts
Author/Authors
Leslie Villalobos، نويسنده , , Tong Ren، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
3
From page
52
To page
54
Abstract
Organic sulfide oxygenation by hydrogen peroxide (H2O2) was effectively accomplished by using iron(III) chloride or iron(III) bromide as the catalyst. The distribution of products between sulfoxide and sulfone is strongly solvent-dependent, and a 100% selectivity for sulfoxide was achieved with FeCl3 in a 1:1 methanol/water mixture.
Keywords
Fe(III) halides , Organic sulfide , Hydrogen peroxide , Catalytic oxygenation
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1319761
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