Title of article :
A 1D polyoxometalate chain built from {Mo16Ni16P24} wheels: Synthesis, structure and magnetism
Author/Authors :
Lifu Wang، نويسنده , , Zhan-Zhong Zhuang، نويسنده , , Ze Chang، نويسنده , , Bo-Yu Zhou، نويسنده , , Tong-Liang Hu، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
A 1D polyoxometalate chain has been constructed from a {Mo16Ni16P24} cluster linked by two {NiO6} edge-shared octahedrons. This chained molybdenum nickel phosphate, Na2[Ni(H2O)8][Ni2(H2O)6][(Mo16O32)Ni16(OH)8(H2PO4)4(HPO4)16(PO4)4(H2O)8]·14H2O (1), crystallizes under hydrothermal reaction and in the monoclinic space group C2/m. In the chain of 1, another {NiO8} polyhedron is capsulated in the {Mo16Ni16P24} wheel. Magnetism analysis shows that there are antiferromagnetic interactions in 1.
Keywords :
Polyoxometalate chain , crystal structure , Magnetism
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
