Title of article :
A MnII5 tetragonal pyramid stabilized by p-tert-butylcalix[8]arene: Synthesis, structure and magnetic property
Author/Authors :
Shangchao Du، نويسنده , , Hongshan Ke، نويسنده , , Yanfeng Bi، نويسنده , , Huaqiao Tan، نويسنده , , Yang Yu، نويسنده , , Jinkui Tang، نويسنده , , Wuping Liao، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
A compound, [Mn5(H4C8A)(OH)2(C3H6NO2)(DMF)5(CH3O)1.5(HCO2) (C2H3O2)0.5]·2DMF·CH3OH (1) (H8C8A = p-tert-butylcalix[8]arene, DMF = N,N′-dimethylformamide), was synthesized by the solvothermal method in the mixed CH3OH/DMF (1:1) solvent. Compound 1 is featured with a tetragonal pyramid-like MnII5 cluster encircled within a calix[8]arene molecule with a ‘pleated loop’ conformation. Magnetic study indicates that the MnII centers exhibit antiferromagnetic interactions.
Keywords :
Calixarenes , manganese , Magnetic property , Crystal growth , Solvothermal synthesis
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
