Author/Authors :
Ekaterina G. Lebed، نويسنده , , Alexander S. Belov، نويسنده , , Alexander V. Dolganov، نويسنده , , Anna V. Vologzhanina، نويسنده , , Agnieszka Szebesczyk، نويسنده , , Elzbieta Gumienna-Kontecka، نويسنده , , Henryk Kozlowski، نويسنده , , Yurii N. Bubnov، نويسنده , , Igor Y. Dubey، نويسنده , , Yan Z. Voloshin، نويسنده ,
Abstract :
Direct template macrobicyclization of three 1,2-cyclohexanedione dioxime molecules with monofunctionalized HO-, H2N- and HOOC-containing phenylboronic acids on Fe2 + and Co2 + ions as a matrix afforded new macrobicyclic iron and cobalt(II) tris-dioximates with reactive apical substituents. The clathrochelates synthesized has been characterized by spectroscopic methods, X-ray crystallography and cyclic voltammetry.
Keywords :
Macrocyclic compounds , Iron complexes , cobalt complexes , Clathrochelates , Ligand reactivity
