Title of article :
An unusual silver–ethynide polymeric chain containing centrosymmetric Ag14 cluster segments stabilized by mixed carboxylate ligands
Author/Authors :
Yun-Peng Xie، نويسنده , , Shaeel A. Al-Thabaiti، نويسنده , , Mohamed Mokhtar، نويسنده , , Thomas C.W. Mak، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
From the reaction of AgCtriple bond; length of mdashCtBu with 9-hydroxy-9-fluorenecarboxylic acid (HL) and AgCF3CO2, we have isolated a new type of organosilver(I) coordination polymeric chain, namely {[Ag14(Ctriple bond; length of mdashCtBu)8(L)2(CF3CO2)4]·2CH3OH}n, which contains centrosymmetric [Ag14(Ctriple bond; length of mdashCtBu)8(CF3CO2)2]4 + cluster segments bridged by pairs of L and trifluoroacetate ligands.
Keywords :
Metal–ligand supramolecular synthon , Organosilver complex , Polymeric coordination chain , Silver(I) ethynide cluster
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
