Title of article :
Positive zero-field splitting in a hexacoordinate nickel(II) complex
Author/Authors :
Alena Packov?، نويسنده , , Jozef Miklovi?، نويسنده , , J?n Titi?، نويسنده , , Marian Koman، نويسنده , , Roman Bo?a، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
Novel molecular Ni(II) complex [Ni(H2O)4(2-Me-Snic)2]·4H2O has been synthesized and structurally characterized. It refers to an elongated tetragonal bipyramid for which a positive zero-field splitting is confirmed by magnetometry. The complex matches the magnetostructural D-correlation for hexacoordinate Ni(II) complexes with moderate structural and magnetic anisotropy Dstr = + 8.60 pm, Dmag = + 4.39 cm− 1.
Keywords :
Nickel(II) complex , crystal structure , Zero-field splitting , Magnetostructurad D-correlation
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
