Title of article
A new octanuclear Fe8 cluster with antiferromagnetic coupling
Author/Authors
Gang Xiong، نويسنده , , Yin-Ling Hou، نويسنده , , JIANZHONG CUI، نويسنده , , Bin Zhao، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
3
From page
89
To page
91
Abstract
A new cluster [Fe8(μ4-O)3(teaH)3(tea)(IBA)6(H2O)3](NO3)3·3H2O (1) (teaH3 = triethylolamine, IBA = isobutyric acid) was synthesized and structurally characterized. The octanuclear cluster is constructed by three Fe4 tetrahedrons via sharing the edges. Magnetic susceptibility measurement indicates that the antiferromagnetic couplings exist between adjacent FeIII centers with zero spin ground state. Cyclic voltammogram exhibit an irreversible redox process.
Keywords
Magnetic property , Antiferromagnetic coupling , Iron cluster , Cyclic voltammogram
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1319993
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