• Title of article

    Crystallization and structure of a binuclear species containing the CoC(OH)OCo moiety

  • Author/Authors

    Etsuko Fujita، نويسنده , , David J. Szalda، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2000
  • Pages
    6
  • From page
    139
  • To page
    144
  • Abstract
    A binuclear species containing the CoC(OH)OCo moiety, [(CoL)2(COOH)](ClO4)3(NCCH3)2 (L=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) was isolated from a CO2 saturated acetonitrile/diethyl ether solution of [CoL(CO2)](ClO4) and its structure was determined. The complex consists of two [CoL]+ units connected by a bridging COOH+ in which the carbon is coordinated to one CoL+ and the non-protonated oxygen to the other CoL+ unit.
  • Keywords
    Macrocycle complexes , Hydroxycarbonyl complexes , cobalt complexes , crystal structures
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2000
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1320112

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1320112