Title of article
Solution configuration of stereogenic hydroxide bridges in the di-μ-hydroxo-tetrakis(S-arginine)dicobalt(III) complex ion
Author/Authors
Nenad Juranic، نويسنده , , Slobodan Macura، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
4
From page
103
To page
106
Abstract
The solution structure of the hydroxide bridges in the anti(N)-Δ-cis(N),cis(O)-Λ-cis(N),cis(O)-di-μ-hydroxo-tetrakis(S-arginine)dicobalt(III) ion complex was determined utilizing 2D NMR NOE spectroscopy. The measured inter-proton distances in the core of the dicobalt complex reveal a non-coplanar, stereogenic, anti(H,Cα) orientation of the bridge hydrogens.
Keywords
cobalt complexes , Dinuclear complexes , Hydroxo bridged complexes , NMR structures
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2000
Journal title
INORGANICA CHIMICA ACTA
Record number
1320160
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