Author/Authors :
Erasmo Chinea، نويسنده , , Dainis Dakternieks، نويسنده , , Andrew Duthie، نويسنده , , Carlo A. Ghilardi، نويسنده , , Pedro Gili، نويسنده , , Alfredo Mederos، نويسنده , , Stefano Midollini، نويسنده , , Annabella Orlandini، نويسنده ,
Abstract :
Reaction of (NH4)VO3 with NTPH3 (N(CH2CH2COOH)3) in water, at controlled pH, allowed the synthesis of (NH4)4[H4V10O28][NTPH2]2·4H2O salt, which has been characterized by spectroscopic measurements (NMR), electrospray mass spectrometry (ESMS) and X-ray diffraction studies. The structure is strongly stabilized by an extensive network of hydrogen bonding interactions which involve the tetraprotonated decavanadate anion, NTPH2 ligand anions, ammonium cations and solvent water molecules.
