Title of article
New palladium(II) complexes of (N,N-dimethylamino)alkoxy-1,3,2-oxazaphospholidine ligands
Author/Authors
A.V Korostylev، نويسنده , , O.G Bondarev، نويسنده , , S.Y Lyubimov، نويسنده , , A.Yu Kovalevsky، نويسنده , , P.V. Petrovskii، نويسنده , , V.A Davankov، نويسنده , , K.N Gavrilov، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
6
From page
1
To page
6
Abstract
New P,N-bidentate aminophosphite ligands OCH2CH2N(R)PO(CH2)nNMe2 (2a R=Me, n=2; 2b R=t-Bu, n=2; 3 R=t-Bu, n=3) have been obtained and characterized. Complexation of all the ligands with [PdCl2(COD)] (COD=1,5-cyclooctadiene) has been investigated. Ligands 2a,b have been found to form mononuclear chelate complexes [PdCl2(PN)]. Ligand 3 forms a binuclear compound [PdCl2(PN)]2, in which molecules 3 act as P,N-bidentate bridges. The obtained compounds have been characterized by multinuclear NMR, IR spectroscopy, mass spectrometry and sedimentation analysis. The molecular structure of [PdCl2L] (L=2b) has been determined by single crystal X-ray diffraction.
Keywords
Aminophosphite complexes , crystal structures , palladium complexes , p , N-ligand complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2000
Journal title
INORGANICA CHIMICA ACTA
Record number
1320350
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