Title of article
Synthesis and catalytic activity of organometallic complexes of palladium(II) with bis-phosphine monosulfides towards ethylene/CO copolymerization
Author/Authors
Gian Paolo Suranna، نويسنده , , Piero Mastrorilli، نويسنده , , Cosimo Francesco Nobile، نويسنده , , Wilhelm Keim، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
6
From page
151
To page
156
Abstract
The neutral and cationic complexes of formula [(CH3)(Cl)Pd(P∧P(S))] and [(CH3)(CH3CN)Pd(P∧P(S))]BF4 [P∧P(S)=Ph2PCH2P(S)Ph2 (dppmS), Ph2P(CH2)2P(S)Ph2 (dppeS)] have been synthesized, characterized and tested as catalysts in the alternating copolymerization of ethylene and carbon monoxide. Both neutral and cationic Pd(II) complexes show η2-(P,S) coordination and cationic complexes exhibit moderate activity.
Keywords
Copolymerization , palladium complexes , Methyl complexes , Catalysis
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2000
Journal title
INORGANICA CHIMICA ACTA
Record number
1320467
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