Title of article
CSi bond cleavage of trihalomethyltrimethylsilane by alkoxo- and aryloxogold or -copper complexes
Author/Authors
Yoko Usui، نويسنده , , Junko Noma، نويسنده , , Masafumi Hirano، نويسنده , , Sanshiro Komiya، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
4
From page
151
To page
154
Abstract
The CSi bond cleavage of trihalomethyltrimethylsilane Me3SiCX3 (X=F, Cl) proceeds smoothly by alkoxo- and aryloxogold(I or III) or -copper(I) complexes Au(OR)L (OR=OCH(CF3)2, OPh), L=PCy3, PPh3, PMe2Ph, PMe3), cis-AuMe2(OPh)L (L=PMePh2, PEt3, PMe2Ph, PMe3), Cu(OR)(PPh3)3 (OR=OCH(CF3)2, OPh) to give trihalomethylgold or -copper complexes Au(CX3)L, cis-AuMe2(CF3)L, or Cu(CF3)L3 with liberation of the corresponding silyl ether Me3SiOR.
Keywords
(Trihalomethyl)gold complexes , C?Si bond cleavage , Alkoxogold complexes , Alkoxocopper complexes , Trihalomethyltrimethylsilane
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2000
Journal title
INORGANICA CHIMICA ACTA
Record number
1320580
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