Title of article
The reactions of [n-Bu4N]2Re2Cl8 with Ph2PCMe2PPh2 and Ph2PC(CH2)2PPh2.: Mononuclear [Re]2+ versus dinuclear [Re2]4+ complexes
Author/Authors
Dastagiri Reddy، Maliki Reddy نويسنده Sri Krishnadevaraya University, Anantapur, A.P., India. , , Phillip E. Fanwick، نويسنده , , Richard A. Walton، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
5
From page
189
To page
193
Abstract
The reactions of [n-Bu4N]2Re2Cl8 with the phosphine ligands Ph2PCMe2PPh2 (2,2-dppp) and Ph2PC(CH2)2PPh2(cdpp), which are derivatives of Ph2PCH2PPh2, lead to the complexes trans-ReCl2(2,2-dppp)2 (1) and Re2Cl4(μ-cdpp)2 (2), respectively, while Re2(μ-O2CCH3)4Cl2 reacts with cdpp to afford trans-Re2(μ-O2CCH3)2Cl2(μ-cdpp)2 (5). The crystal structures of 1 and 5 have been determined, that of 5 being only the second one reported for a complex of cdpp.
Keywords
Mononuclear rhenium(II) complexes , Dirhenium(II) complexes , Bidentate phosphines , Metal?metal multiple bonds
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2001
Journal title
INORGANICA CHIMICA ACTA
Record number
1320723
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