Author/Authors :
David A Voss Jr.، نويسنده , , Lisa A Buttrey-Thomas، نويسنده , , Thomas S Janik، نويسنده , , Melvyn Rowen Churchill، نويسنده , , Janet R Morrow، نويسنده ,
Abstract :
The kinetics of decomposition of several lanthanide(III) hexaaza Schiff-base macrocyclic complexes is examined in aqueous solution. For a given macrocycle, decomposition of the Schiff-base into component amine and carbonyl compound is dependent on which lanthanide ion is used. For the L1 complexes (L1=C22H26N6) the rate of decomposition increases as: Eu(L1)3+
Keywords :
Macrocycle complexes , Schiff-base complexes , crystal structures , Lanthanide complexes
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA