Title of article
Comproportionation and redox catalyzed isomerization of Cu(II)(1R,4S,8R,11S-1,4,8,11-tetramethyl-1,4,8,11-tetraaza-cyclotetradecane)2+ in aqueous solutions
Author/Authors
Eric Maimon، نويسنده , , Israel Zilbermann، نويسنده , , Gilad Golub، نويسنده , , Arkady Ellern، نويسنده , , Alexander I Shames، نويسنده , , Haim Cohen، نويسنده , , Dan Meyerstein، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
8
From page
65
To page
72
Abstract
The complex Cu(II)(1R,4S,8R,11S-tmc)2+ comproportionates and isomerizes in the presence of excess of ligand and Cu° in alkaline aqueous solutions to yield Cu(II)(1R,4R,8S,1S-tmc)2+. The visible and EPR spectra of the two complexes as well as their electrochemical properties are reported. The complexes Cu(II)(1R,4R,8S,11S-tmc)(ClO4)2 and [Cu(II)(1R,4S,8R,11S-tmc)]2N3(ClO4)3 were isolated and crystallographically characterized.
Keywords
copper , Tetramethylcyclam , Comproportionation , Redox catalyzed isomerization
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2001
Journal title
INORGANICA CHIMICA ACTA
Record number
1320999
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