• Title of article

    Synthesis and characterisation of the halogenated azanonaboranes [(iPrNH2)B8H10XNHiPr] (X=Cl, Br, I) and their unexpected hydrolysis to hypho-[B5H10(μ-NHiPr)]

  • Author/Authors

    Claudia Bauer، نويسنده , , Detlef Gabel، نويسنده , , Thomas D McGrath، نويسنده , , Udo D?rfler، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2002
  • Pages
    5
  • From page
    181
  • To page
    185
  • Abstract
    Treatment of [(iPrNH2)B8H11NHiPr] with elemental halogen affords the 8-exo-halogen-substituted derivatives [(iPrNH2)B8H10XNHiPr] (X=Cl, Br, I). The structures of all three compounds are confirmed by NMR spectroscopy and mass spectrometry, and (for X=Br) by an X-ray diffraction study. The bromoazanonaborane undergoes hydrolytic decomposition to the new five-vertex compound [B5H10(μ-NHiPr)] of hypho-type structure.
  • Keywords
    Halogenation , hypho-Clusters , Hydrolysis , crystal structures , Azanonaboranes
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2002
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1321259

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1321259