Author/Authors :
Igor L. Eremenko، نويسنده , , Aleksei E Malkov، نويسنده , , Aleksei A. Sidorov، نويسنده , , Irina G. Fomina، نويسنده , , Grygory G. Aleksandrov، نويسنده , , Sergei E. Nefedov، نويسنده , , Gennady L. Rusinov، نويسنده , , Oleg N. Chupakhin، نويسنده , , Vladimir M. Novotortsev، نويسنده , , Vladimir N. Ikorskii، نويسنده , , Ilya I. Moiseev، نويسنده ,
Abstract :
Microporous one-dimensional material was synthesized by reacting Ni-9 cluster compound Ni9(HOOCCMe3)4(μ4-OH)3(μ3-OH)3(OOCCMe3)12 with organic ligand 3-(3,5-dimethylpyrazol-1-yl)-6-(3,5-diamino-1,3,4-thiadiazolyl)-1,2,4,5-tetrazine) (L). According to X-ray data, the nano-sized endless tubes of the material consist of stacked cationic Ni(II) octa-nuclear cyclic complexes of formula [Ni8(μ-OH2)4(μ-OOCCMe3)4(η2-OOCCMe3)(OOCCMe3)10L4]+ and pivalate anions ordered regularly aside the tubes. The channels of the tubes are filled with acetonitrile molecules forming an inclusion compound.
Keywords :
One-dimensional microporous material , Self-assembly , Nano-sized tubes , Pivalate ligand , nickel complexes
