Synthesis and structure of [(Ph3P)2Ag(μ-Cl)(μ-SC{O}Ph)In(SC{O}Ph)2]

The synthesis and structure of the hetero-bimetallic compound [(Ph3P)2Ag(μ-Cl)(μ-SC{O}PhS)In(SC{O}Ph)2] have been reported. The compound was synthesized by reacting [(Ph3P)2AgCl], InCl3·4H2O and NaSC{O}Ph in the ratio 1:1:3 in a mixture of solvents. The structure of the compound has been determined by X-ray crystallography. The compound contains a nonplanar AgClSIn core.