• Title of article

    A penta-coordinated zinc complex containing a bio-mimetic NS2S′2 (thiolate–thioether) ligand

  • Author/Authors

    Henning Nekola، نويسنده , , Dieter Rehder، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2002
  • Pages
    3
  • From page
    467
  • To page
    469
  • Abstract
    The pentadentate, dianionic ligand 2,6-bis(2′-mercaptophenylthio)dimethylpyridine, NS2S′2 2−, which contains two thioether (S) and two thiophenolate (S′) functions, reacts with [V2(μ-Cl)3(thf)6]2[Zn2Cl6] to form the zinc complex [Zn(NS2S′2)]·CH2Cl2. The relevance of this compound as a model for ZnS and ZnS′ binding in biomolecules is addressed.
  • Keywords
    Zinc complexes , Zinc in biology , Thioether coordination , Thiolate coordination
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2002
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1321436