Title of article
Synthesis of enol esters catalysed by ‘early–late’ Ti–Ru complexes
Author/Authors
Pierre Le Gendre، نويسنده , , Virginie Comte، نويسنده , , Amélie Michelot، نويسنده , , Claude Mo?̈se، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
289
To page
292
Abstract
The titane–ruthenium heterobimetallic compounds (p-cymene)[(η5-C5H5)(μ-η5:η1-C5H4(CH2)mPR2)TiCl2]RuCl24–6 have been revealed to be quite good catalysts for the addition of formic acid to 1-hexyne and phenylacetylene. These preliminary results led us to synthesize new tetrametallic complexes 10–12 via the reaction of the titanocene phosphanes 1–3 with the polymer [Ru(CO)2(μ-O2CH)]n. Their catalytic ability for the enol esters formation has been studied.
Keywords
titanocene , Ruthenium , Bimetallic complexes , Enol esters
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2003
Journal title
INORGANICA CHIMICA ACTA
Record number
1321623
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