• Title of article

    Facile reduction of early transition metal halides with nonconventional, mild reductants. 6. A new, lower-temperature, solid-state synthesis of the cluster hexamolybdenum dodecachloride Mo6Cl12 from MoCl5, via chloromolybdic acid, (H3O)2[Mo6(μ3-Cl)8Cl6] ·

  • Author/Authors

    Daniel N.T. Hay، نويسنده , , Juan A. Adams، نويسنده , , Jason Carpenter، نويسنده , , Stephanie L. DeVries، نويسنده , , John Domyancich، نويسنده , , Bruce Dumser، نويسنده , , Shawn Goldsmith، نويسنده , , Melissa A. Kruse، نويسنده , , Angela Leone، نويسنده , , Farid Moussavi-Harami، نويسنده , , Jennifer A. O’Brien، نويسنده , , Jennifer R. Pfaffly، نويسنده , , Michael Sylves، نويسنده , , Parisa Taravati، نويسنده , , Jacob ، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    5
  • From page
    644
  • To page
    648
  • Abstract
    Reduction of MoCl5 with Bi in a sealed borosilicate ampule at 350 °C, followed by sublimation of by-product BiCl3 and addition of aqueous hydrochloric acid, yielded chloromolybdic acid, (H3O)2Mo6(μ3-Cl)8Cl6 · 6H2O, in 80% yield (unoptimized) after double recrystallization. Chloromolybdic acid was thermolyzed to Mo6Cl12 in 95% yield.
  • Keywords
    Molybdenum dichloride , Molybdenum pentachloride reduction , Hexamolybdenum dodecachloride , Bismuth , Chloromolybdic acid
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2004
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1321964

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1321964