• Title of article

    Photolysis of the ion pair [PtIV(NH3)5Cl]3+S2O82−: reduction of platinum(IV) induced by outer-sphere charge transfer excitation

  • Author/Authors

    Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    3
  • From page
    2401
  • To page
    2403
  • Abstract
    The ion pair [PtIV(NH3)5Cl]3+S2O82− shows a S2O82− → [Pt(NH3)5Cl]3+ outer-sphere charge transfer (OSCT) absorption at λmax=267 nm. OSCT excitation leads to the reduction of Pt(IV) by S2O82− to Pt(II) with φ=3×10−3 at λirr=280 nm.
  • Keywords
    Electronic spectra , Charge transfer , Platinum , Peroxide , Photochemistry
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2004
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1322188

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1322188