Title of article :
Solvent roles in metal ion coordination: the NiCl2 O-solvates, NiCl2 · 4MeOH, NiCl2 · 2MeOH · 0.5dioxan and NiCl2 · 2H2O · 2dioxan
Author/Authors :
Nicole L. Armanasco، نويسنده , , Murray V. Baker، نويسنده , , David H. Brown، نويسنده , , Jack M. Harrowfield، نويسنده , , Brian W. Skelton، نويسنده , , Allan H. White، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Abstract :
Low-temperature, single crystal X-ray structural characterisations of trans-[NiCl2(HOMe)4], trans-O-[Ni(MeOH)2(μ-Cl)(2/2)2](∞∣∞) · 0.5dioxan and trans-trans-[Ni(H2O)2Cl2(O-dioxan-O)(2/2)](∞∣∞) · dioxan are recorded, offering intriguing insights into O-donor/Ni(II) relativities. All nickel atoms in all structures are located on crystallographic inversion centres, the last two compounds being one-dimensional polymers.
Keywords :
Nickel(II) coordination , Solvation , crystal structures
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
