Title of article
Convenient synthesis of copper (I) thiolates and related compounds
Author/Authors
Lynda M. Nguyen، نويسنده , , Megan E. Dellinger، نويسنده , , Jeffrey T. Lee، نويسنده , , Ronald A. Quinlan، نويسنده , , Arnold L. Rheingold، نويسنده , , Robert D. Pike، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
6
From page
1331
To page
1336
Abstract
Copper (I) salts of various anions including thiolates, diethyl dithiocarbamate, diethyl dithiophosphate, trithiocyanurate, 1-cyano-3-methylisothiourea, 2-aminothiazole, and tetrakis(1-imidazolyl)borate are conveniently synthesized by reducing copper (II) sulfate in aqueous ammonia. The addition of phosphine ligands to several of the products is demonstrated, and the crystal structure of [Cu2(MBT)2(DPPE)3] · Et2O (MBT = 2-mercaptobenzothiazolate, DPPE = 1,2-bis(diphenylphosphino)ethane) is reported.
Keywords
Copper (I) , phosphines , Dithiophosphates , Dithiocarbamates , Tetrakis(1-imidazolyl)borate , Thiolates
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2005
Journal title
INORGANICA CHIMICA ACTA
Record number
1322785
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