Title of article :
Synthesis and structural characterization of two monomeric potassium phenolates
Author/Authors :
Marcus L. Cole، نويسنده , , Luke T. Higham، نويسنده , , Peter C. Junk، نويسنده , , Kathryn M. Proctor، نويسنده , , Janet L. Scott، نويسنده , , Christopher R. Strauss، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Reaction of 2,6-dibenzylphenol and 2,6-bis-(2-methoxybenzyl)phenol with potassium hexamethyldisilazide in the presence of 18-crown-6 yielded [K(18-crown-6)(Odbp)] and [K(18-crown-6)(OdbpOMe)], respectively. Both compounds were mononuclear with seven-coordinate potassium and displayed C–H⋯O and C–H⋯π intermolecular hydrogen bonding.
Keywords :
Potassium , Crown ethers , Phenolates , crystal structures
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
