Title of article
Long-range superexchanged magnetic interaction observed in heterometallic complex: {[FeII(Tpms)(CN)3][MnII(H2O)2(DMF)2]} · DMF
Author/Authors
Zhi-Guo Gu، نويسنده , , Jing-Lin Zuo، نويسنده , , You Song، نويسنده , , Chenghui Li، نويسنده , , Yi-Zhi Li، نويسنده , , Xiao-Zeng You، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
5
From page
4057
To page
4061
Abstract
A new tri-cyanometalate building block for heterometallic complexes, [PPh4]2[FeII(Tpms)(CN)3] (2) (PPh4 = tetraphenylphosphonium; Tpms = tris(pyrazolyl) methanesulfonate), has been prepared. Using it as a building block, a one-dimensional chain compound, {[FeII(Tpms)(CN)3][MnII(H2O)2( DMF)2]} · DMF (3), has been synthesized and structurally characterized. The magnetic properties of 3 correspond to a ferromagnetic chain with weak long-range superexchanged magnetic interaction between the high-spin manganese(II) ions.
Keywords
Iron , Chain structure , Superexchanged magnetic interaction , Cyanide ligands , Polynuclear complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2005
Journal title
INORGANICA CHIMICA ACTA
Record number
1323111
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